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octahedral cluster : ウィキペディア英語版
octahedral cluster
Octahedral clusters are inorganic or organometallic cluster compounds composed of six metals in an octahedral array.〔Eric J. Welch and Jeffrey R. Long ''Atomlike Building Units of Adjustable Character: Solid-State and Solution Routes to Manipulating Hexanuclear Transition Metal Chalcohalide Clusters'' in Progress in Inorganic Chemistry, Volume 54 Kenneth D. Karlin ISBN 0-471-72348-7 2005 (Link )〕 Many types of compounds are known, but all are synthetic.
==Octahedral chalcogenide and halide clusters==
These compounds are bound together by metal-metal bonding as well as two kinds of ligands. Ligands that span the faces or edges of the M6 core are labeled Li, for ''inner'' (innen in the original German description), and those ligands attached only to one metal are labeled outer, or La for ''ausser''.〔 Typically, the outer ligands can be exchanged whereas the bridging ligands are more inert toward substitution.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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